All my fault
During one of the many, many wakeful periods I experienced last night I realized why the orange peel didn't work (or one reason; I suspect the peel isn't very "orangy").
I had a clear memory of me turning back to the sink for a second cup of water, thus rendering the syrup a 1:1 water/sugar mixture, rather than the 1:2 one called for.
Just a brain fade, probably because there are many distractions in my kitchen, but now I need to decide whether or not to re-syrup them or feed 'em to the compost and start over.
I know where more oranges are, anyhow. . .
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